Blastoise could still use Withdraw to dodge Dragon Rage, so Charizard hurled Blastoise into the ground with Seismic Toss, defeating it and leaving Ash as the winner. During its time in the Charicific Valley, Charizard took the role of Charla’s bodyguard, and the two seem to have a sort of romantic relationship with each other. Liza occasionally visited the Dragon Holy Land in Blackthorn City with the two Charizard. , which coincidentally occurred when Ash was there for his final Johto Gym Neo Geo emulator battle. Charizard helped Ash, Clair, Pikachu and Dragonair calm the wild Dragonite that was rampaging in the Dragon Holy Land.
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Once Ash released the captured originals to confront the clones, Charizard battled the cloned Charizard once again but ended the battle to cry for Ash after his sacrifice to try and stop the battle between Mew and Mewtwo. After Mewtwo departed with Mew and the clones upon witnessing Ash’s resurrection, it erased these actions from the memories of all people and Pokémon present, returning Charizard to its familiar disobedience.
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It finally subdued its opponent by using Rage and Flamethrower. Charmander made its Gym Battle debut in the next episode, where it defeated Erika’s Weepinbell after burning Razor Leaf and then striking a powerful Skull Bash.
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Magmar dropped Charizard into the lava, but Charizard regained the upper hand by dazing Magmar with an aerial Submission attack and then knocking it out with its powerful Seismic Toss. In Primeape Goes Bananas, Charmander battled a berserk Primeape.
In the next episode, Charizard refused to help dam the volcano, but changed its mind after seeing Blaine’s powerful Magmar contributing. After working together, the duo was left with a burning desire to test each other’s strength. Blaine permitted a battle at the peak of the volcano, and the two seemed evenly matched.
Thinking outside the box, Ash told Charizard to superheat the field, which forced Blastoise to spend time cooling the molten rock. This created a huge steam cloud and allowed Charizard to seize Blastoise at close range.